The hours people clock and PTO hours which you approve will be on the timekeeping report.  The PTO hours only show if you approve them.  The clocked hours will show whether or not you approve them, and they will say if they are approved.

Go to the Reports tab and select Employee Timetracking Report.

Then click on the pay cycle name.

Scroll to the preferred pay period.

You can either copy the hours over to payroll by hand or save them as a CSV file.  Remember, PTO hours will only be there if you approved them.